Product ID:LEAD-ACID BATTERY,UB-72
MSDS Date:02/01/1996
FSC:6140
NIIN:01-193-6579
MSDS Number: CFYZQ

EXIDE CORP.-GENERAL BATTERY CORP

645 PENN STREET
READING, PA 19601
US

Emergency Phone: 215-378-0527

Info Phone: 215-378-0527/610-378-0500

Cage: 08163

EXIDE CORP.-GENERAL BATTERY CORP

READING, PA 19601 US

Telephone: 215-378-0527/800-424-9300(CHEMTREC)

Cage: 08163

LEAD (SARA 313) (CERCLA)/LEAD,LEAD OXIDE,LEAD SULFATE

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 53%

OSHA PEL SEE 1910.1025

ACGIH TLV: 0.05MG/M3, A3; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ANTIMONY (SARA 313) (CERCLA)

CAS: 7440-36-0

RTECS: CC4025000

Fraction By Weight: 0.2%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG (SB)/M3; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ARSENIC (SARA 313) (CERCLA)

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: 0.003%

OSHA PEL SEE 1910.1018

ACGIH TLV: 0.01 MG/M3, A1; 9596

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CALCIUM, METAL

CAS: 7440-70-2

RTECS: EV8040000

Fraction By Weight: 0.02%

TIN

CAS: 7440-31-5

RTECS: XP7320000

Fraction By Weight: 0.06%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9596

SULFURIC ACID (SARA 302/313) (CERCLA)/ELECTROLYTE

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 30 - 40%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3/3 STEL; 9596

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

POLYPROPYLENE (PRINCIPAL CASE MATERIAL OF AUTOMOTIVE AND

CAS: 9003-07-0

RTECS: TR5000000

Fraction By Weight: 5 - 6%

HARD RUBBER

SILICONE DIOXIDE (GEL CELL BATTERIES)/SILICA, CRYSTALLINE -

CAS: 60676-86-0

RTECS: VV7328000

Fraction By Weight: 3 - 5%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST;9596

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT RELEVANT.
Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, LUNG, GI
TRACT. ACUTE- LEAD MAY CAUSE GI UPSET, DIARRHEA, CRAMPING &
FATIGUE. SULFURIC ACID MAY CAUSE EYE, SKIN & RESPIRATORY TRACT
IRRITATION, BURNS, CORNEAL & LUNG DAMA GE. CHRONIC- LEAD MAY CAUSE
ANEMIA, KIDNEY & NERVOUS SYSTEM DAMAGE. ACID CAN CAUSE BRONCHITIS,
EROSION OF TOOTH ENAMEL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:GI UPSET, LOSS OF APPETITE, DIARRHEA,
CONSTIPATION, CRAMPING, LACK OF SLEEP, FATIGUE, SEVERE IRRITATION,
BURNS, CORNEAL AND LUNG DAMAGE, BLINDNESS, ULCERATION, WRIST DROP,
REPRODUCTIVE CHANGES
Medical Cond Aggravated by Exposure:LEAD AND ITS COMPOUNDS CAN
AGGRAVATE CHRONIC FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASES.
CONTACT OF SULFURIC ACID WITH SKIN MAY AGGRAVATE DISEASES SUCH AS
ECZEMA. ACID MIST AGGRAVATES LUNG DISEASE

First Aid:OBTAIN MEDICAL ATTENTION IMMEDIATELY IN ALL CASES OF
EXPOSURE. EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES.
KEEP EYELIDS OPEN. INHALATION:REMOVE TO FRESH AIR IMMEDIATELY. IF
BREATHING IS DIF FICULT, PROVIDE OXYGEN. INGESTION:DO NOTINDUCE
VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER OR MILK.

Flash Point:NON-FLAMMABLE
Lower Limits:4.1%HYDROGEN
Upper Limits:74.2HYDROGEN
Extinguishing Media:USE CARBON DIOXIDE, SAND, HALON/DRY CHEMICAL. WATER
APPLIED TO ELECTROLYTE GENERATES HEAT AND CAUSES IT TO SPATTER.
Fire Fighting Procedures:WEAR ACID-RESISTANT CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:BATTERY CELLS MAY RUPTURE WHEN EXPOSED TO
EXCESSIVE HEAT. THIS COULD RESULT IN RELEASE OF CORROSIVE
MATERIALS. HYDROGEN GAS, IF PRESENT, IS EXPLOSIVE/FLAMMABLE.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. VENTILATE AREA.
REMOVE IGNITION SOURCES (H2 MAY BE PRESENT). CONTAIN BY DIKING AND
COVER SPILL WITH SODA ASH OR QUICKLIME. MIX WELL. CHECK THAT
MIXTURE IS NEUTRAL. COLLECT AND PLACE IN A DRUM. DO NOT FLUSH TO
SEWER.
Neutralizing Agent:SODA ASH (SODIUM CARBONATE), QUICKLIME (CALCIUM
OXIDE)

Handling and Storage Precautions:STORE NEAR EYEWASH FOUNTAIN AND SAFETY
SHOWER. STORAGE AREA SHOULD BE EQUIPPED WITH A DRAIN WHICH CAPTURES
SPILLS OF ACID FOR PROPER DISPOSAL.
Other Precautions:KEEP TERMINALS COVERED. AVOID SHORTING BATTERIES. DO
NOT CRACK/OVERCHARGE BATTERIES. KEEP LIGHTED CIGARETTES, SPARKS,
AND FLAMES AWAY FROM BATTERIES. KEEP OUT OF REACH OF CHILDREN.
AVOID METALLIC ARTI CLES TO CONTACT TERMINALS OF A BETTERY.

Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE
NIOSH-APPROVED ACID-MIST FILTER RESPIRATOR IF 1 MG/M3 TWA IS
EXCEEDED (ACID).
Ventilation:ADEQUATE GENERAL VENTILATION
Protective Gloves:RUBBER
Eye Protection:SPLASH-PROOF CHEMICAL GOGGLES
Other Protective Equipment:RUBBER APRON AND BOOTS. EYES WASH STATION
AND SAFETY SHOWER. USE ACID-PROOF CLOTHING FOR MAJOR SPILLS.
Work Hygienic Practices:REMOVE METALLIC JEWELRY-SHOCK POTENTIAL. WASH
THOROUGHLY AFTER HANDLING AND BEFORE EATING AND DRINKING.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN.

HCC:Z4
NRC/State Lic Num:NOT RELEVANT
Spec Gravity:1.23-1.35(ACID)
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVENT
Appearance and Odor:BATTERY CONTAINING SULFURIC ACID AND LEAD.

Stability Indicator/Materials to Avoid:YES
COMBUSTIBLES, ORGANIC MATERIALS, METALS, REDUCING AGENTS, SULFUR
TRIOXIDE, WATER, BASES
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, OVERCHARGING,
SMOKING, SPARKS
Hazardous Decomposition Products:LEAD OXIDE, HYDROGEN, SULFUR DIOXIDE,
SULFUR TRIOXIDE, METAL FUMES, SULFURIC ACID MIST

Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. OBSERVE ALL FEDERAL,
STATE AND LOCAL ENVIRONMENTAL REGULATIONS FOR ACID OR LEAD SCRAP.
SEND BATTERIES TO LEAD SMELTER FOR RECLAMATION FOLLOWING APPLICABLE
FEDERAL, STATE AN D LOCAL REGULATIONS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.